Start by mounting the stick which should be automatic in GUI.
mount|grep /dev/sd
should tell what is the /dev/USBSTICK
isohybrid image.iso
dd if=image of=/dev/USBSTICK bs=1024
First unmount the CD/DVD and then
dd if=/dev/DRIVE of=image.iso
DRIVE can be /dev/dvd /dev/cdrom or /dev/scd0 depending on the CD/DVD.
dd if=/dev/DRIVE (see above) of=IMAGE.iso conv=noerror
maybe ddrescue should be used instead of dd.